n-Hexylzinc bromide
n-Hexylzinc bromide
CAS: 124397-96-2
Molecular Formula: C6H13BrZn
n-Hexylzinc bromide - Names and Identifiers
n-Hexylzinc bromide - Physico-chemical Properties
| Molecular Formula | C6H13BrZn |
| Molar Mass | 230.46 |
| Density | 0.965g/mLat 25°C |
| Flash Point | 1°F |
| Exposure Limit | ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| Storage Condition | 2-8°C |
| Sensitive | Air Sensitive |
n-Hexylzinc bromide - Risk and Safety
| Risk Codes | R19 - May form explosive peroxides R22 - Harmful if swallowed R36/38 - Irritating to eyes and skin. R40 - Limited evidence of a carcinogenic effect R36/37 - Irritating to eyes and respiratory system. R14 - Reacts violently with water R11 - Highly Flammable |
| Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33 - Take precautionary measures against static discharges. S36 - Wear suitable protective clothing. S36/37 - Wear suitable protective clothing and gloves. |
| UN IDs | UN 3399 4.3/PG 2 |
| WGK Germany | 1 |
| Hazard Class | 4.3 |
n-Hexylzinc bromide - Introduction
n-Hexylzinc bromide(n-Hexylzinc bromide) is an organic compound with the formula C6H13ZnBr. It is a colorless to pale yellow liquid, flammable.
n-Hexylzinc bromide can be used as reagents and catalysts for organic synthesis. It can be used in the synthesis of organic zinc reagents such as hexyl zinc, hexyl indium bromide, etc. These organozinc reagents can undergo various reactions in organic synthesis, such as nucleophilic substitution, addition, reduction, etc.
The preparation of n-Hexylzinc bromide is usually obtained by reacting zinc bromide with hexyl copper. First, zinc bromide and metal zinc are reacted in dimethylformamide (DMF), and then reacted with hexylcupric bromide to form n-Hexylzinc bromide.
n-Hexylzinc bromide has certain security risks. It is a flammable liquid and may burn when in contact with oxygen in the air. It is irritating to the eyes, skin and respiratory tract and requires protection when exposed. In the use and storage need to comply with the relevant safety procedures, and properly stored to prevent leakage and fire.
n-Hexylzinc bromide can be used as reagents and catalysts for organic synthesis. It can be used in the synthesis of organic zinc reagents such as hexyl zinc, hexyl indium bromide, etc. These organozinc reagents can undergo various reactions in organic synthesis, such as nucleophilic substitution, addition, reduction, etc.
The preparation of n-Hexylzinc bromide is usually obtained by reacting zinc bromide with hexyl copper. First, zinc bromide and metal zinc are reacted in dimethylformamide (DMF), and then reacted with hexylcupric bromide to form n-Hexylzinc bromide.
n-Hexylzinc bromide has certain security risks. It is a flammable liquid and may burn when in contact with oxygen in the air. It is irritating to the eyes, skin and respiratory tract and requires protection when exposed. In the use and storage need to comply with the relevant safety procedures, and properly stored to prevent leakage and fire.
Last Update：2024-04-10 22:29:15
